Search results for "Thermodynamic process"
showing 8 items of 8 documents
Modeling of Elemental Species
2005
Interface thermodynamic model for low pressure evaporation
1979
Fractional-Order Thermal Energy Transport for Small-Scale Engineering Devices
2014
Fractional-order thermodynamics has proved to be an efficient tool to describe several small-scale and/or high-frequency thermodynamic processes, as shown in many engineering and physics applications. The main idea beyond fractional-order physics and engineering relies on replacing the integer-order operators of classical differential calculus with their real-order counterparts. In this study, the authors aim to extend a recently proposed physical picture of fractional-order thermodynamics to a generic 3D rigid heat conductor where the thermal energy transfer is due to two phenomena: a short-range heat flux ruled by stationary and nonstationary transport equations, and a long-range thermal …
Gibbs equation in the nonlinear nonequilibrium thermodynamics of dilute nonviscous gases
2003
AbstractThis paper deals with the derivation of the Gibbs equation for a nonviscous gas in the presence of heat flux. The analysis aims to shed some light on the physical interpretation of thermodynamic potentials far from equilibrium. Two different definitions for the chemical potential and thermodynamic pressure far from equilibrium are introduced: nonequilibrium chemical potential and nonequilibrium thermodynamic pressure at constant heat flux q and nonequilibrium chemical potential and nonequilibrium thermodynamic pressure at constant J = Vq, where V is the specific volume.
A non-local model of thermal energy transport: The fractional temperature equation
2013
Abstract Non-local models of thermal energy transport have been used in recent physics and engineering applications to describe several “small-scale” and/or high frequency thermodynamic processes as shown in several engineering and physics applications. The aim of this study is to extend a recently proposed fractional-order thermodynamics ( [5] ), where the thermal energy transfer is due to two phenomena: A short-range heat flux ruled by a local transport equation; a long-range thermal energy transfer that represents a ballistic effects among thermal energy propagators. Long-range thermal energy transfer accounts for small-scale effects that are assumed proportional to the product of the in…
A bending theory of thermoelastic diffusion plates based on Green-Naghdi theory
2017
Abstract This article is concerned with bending plate theory for thermoelastic diffusion materials under Green-Naghdi theory. First, we present the basic equations which characterize the bending of thin thermoelastic diffusion plates for type II and III models. The theory allows for the effect of transverse shear deformation without any shear correction factor, and permits the propagation of waves at a finite speed without energy dissipation for type II model and with energy dissipation for type III model. By the semigroup theory of linear operators, we prove the well-posedness of the both models and the asymptotic behavior of the solutions of type III model. For unbounded plate of type III…
Criteria for validity of thermodynamic equations from non-equilibrium molecular dynamics simulations
2008
Abstract The assumption of local equilibrium is validated in four different systems where heat and mass are transported. Mass fluxes up to 13 kmol / m 2 s and temperature gradients up to 10 12 K / m were used. A two-component mixture, two vapor–liquid interfaces, a chemical reaction in a temperature gradient and gas adsorbed in zeolite were studied using non-equilibrium molecular dynamics simulations. In all cases, we verified that thermodynamic variables obeyed normal thermodynamic relations, with an accuracy better than 5%. The heat and mass fluxes, and the reaction rate were linearly related to the driving forces. Onsager's reciprocal relations were validated for two systems. Equipartiti…
Constraining the Equation of State of Neutron Stars with Genral Relativity
2005
When a radio pulsar breakes down by virtue of magnetodipole emission, its gravitational mass decreases accordingly. If the pulsar in hosted in a binary system, this mass loss will increase the orbital period of the system. We show that this relativistic effect can be indeed observable if the NS is fast and magnetized enough and that, if observed, it will help to put tight constraints on the equation of state of ultradense matter.